early 15c., "mighty, very powerful, possessed of inherent strength," from Latin potentem (nominative potens) "powerful," present participle of posse "be able, be powerful," a contraction of potis esse "be powerful, be master," from potis "powerful, able, capable; possible;" of persons, "better, preferable; chief, principal; strongest, foremost," from PIE root *poti- "powerful; lord." "The exact process leading from potis + esse to the paradigm of posse is disputed" [de Vaan].
The meaning "having sexual power, capable of orgasm in sexual intercourse" (of men) is recorded by 1893.
posse "be able, be powerful," a contraction of potis esse "be powerful, be master,"